PHASE EQUILIBRIA AT THE ISOTHERMAL SECTIONS OF THE QUASI-TERNARY SYSTEMS Ag(Cu)2X–PbX–SNX2 (X=S, Se) AT ROOM TEMPERATURE

Authors

DOI:

https://doi.org/10.32782/pcsd-2021-1-4

Keywords:

semiconductors, isothermal sections, phase diagrams, X-ray phase analysis

Abstract

The isotermal sections of the quasi-ternary systems Ag(Cu)2X–PbX–SnX2 (X=S, Se) at room temperature were investigated by X-ray phase analysis. No intermediate quaternary phases were found in the systems. Intermediate alloys on the PbSe–SnSe2 side are three-phase, the alloys in the triangles bounded by this side are four-phase. The reason for this is that the PbSe–SnSe2 section is non-quasi-binary causing an unusual tetrahedration of the Ag(Cu)–Pb–Sn–Se systems that is different from the sulfide systems.

References

Iyer R.G., Aitken J.A., Kanatzidis M.G. Noncentrosymmetric cubic thio- and selenogermanates: A0.5M1.75GeQ4 (A = Ag, Cu, Na; M = Pb, Eu; Q = S, Se). Solid State Sciences. 2004. V.6. P. 451–459.

Parasyuk O.V., Piskach L.V., Romanyuk Y.E., Olekseyuk I.D., Zaremba V.I., Pekhnyo V.I. Phase relations in the quasi-binary Cu2GeS3–ZnS and quasi-ternary Cu2S–Zn(Cd)S–GeS2 systems and crystal structure of Cu2ZnGeS4. J. Alloys Comp. 2005. V. 397. P. 85–94.

Jumas J.-C., Ribes M., Philippot E., Maurin M. Etude du systeme ternaire Pb–Sn–S. C.R. Acad. Sci. Ser. C. 1972. V. 275 C. P. 269–272.

Кохан О.П. Взаємодія в системах Ag2X–BIVX2 (BIV – Si, Ge; X – S, Se) і властивості сполук. Автореф. дис. … канд. хім. наук. Ужгородський держ. Ун-т. Ужгород, 1996. 21 с.

Ворошилов Ю.В., Евстигнеева Т.Л., Некрасов И.Я. Кристаллохимические таблицы тройных халькогенидов. Москва : Наука, 1989. 224 с.

O. Amiel, D.C. Frankel, H. Wada. Crystal structure of a new silver thiostannate Ag4Sn3S8. J. Solid State Chemistry. 1995. V. 116. P. 409–421.

L.D. Gulay, I.D. Olekseyuk, O.V. Parasyuk. Crystal structure of β-Ag2SnSe6. J. Alloys Comp. 2002. V. 339. P. 113–117.

J. Rivet, J. Flahaut, P. Laruelle. Les etudes du systemes binaires Cu2S–SnS2 et Cu2Se–SnSe2. C.R. Acad. Sci. 1967. V. 257. P. 161–164.

M. Khanafer, J. Rivet, J. Flahaut. Etude du systeme ternaire Cu–Sn–S. Diagrammes d’equilibre des systemes Cu2S–SnS, Cu2S–Sn2S3 et Cu2S–SnS2. Etude cristallographique des composes Cu4SnS4, Cu2SnS3, Cu2Sn4S9 et Cu4Sn3S8. Bull. Soc. Chim. Fr. 1974. P. 2670–2676.

N. Wiberg. Lehrbuch der Anorganischen Chemie. Berlin: Walter de Gruyter, 1995. P. 1838-1841.

Olekseyuk I.D., Piskach L.V., Zhbankov O.Ye., Parasyuk O.V., Kogut Yu.M. Phase diagrams of the quasi-binary systems Cu2S–SiS2 and Cu2SiS3–PbS and the crystal structure of the new quaternary compound Cu2PbSiS4. J. Alloys Comp. 2005. V. 399. P. 140-154.

Published

2021-05-11

How to Cite

ОЛЕКСЕЮК, І., КОГУТ, Ю., & ПІСКАЧ, Л. (2021). PHASE EQUILIBRIA AT THE ISOTHERMAL SECTIONS OF THE QUASI-TERNARY SYSTEMS Ag(Cu)2X–PbX–SNX2 (X=S, Se) AT ROOM TEMPERATURE. Problems of Chemistry and Sustainable Development, (1), 26–30. https://doi.org/10.32782/pcsd-2021-1-4

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