FOUR-ELEMENTS CHALCOGENIDES OF THE SYSTEMS Tl2X–BIIX–DIVX2 (BII – Cd, Hg, DIV– Si, Ge; X – Se, Te)
DOI:
https://doi.org/10.32782/pcsd-2021-2-5Keywords:
thallium-containing quaternary chalcogenides, phase equilibria, crystal structure, X-ray phase analysisAbstract
Isothermal sections of the Tl2Se–CdSe–Ge(Sn)Se2 systems at 570 K were investigated by XRD results. The formation of the two quaternary compounds was found in the Tl2Se – CdSe – GeSe2 system at the annealing temperature in the state of thermodynamic equilibrium. Tl2CdGeSe4 forms at the Tl2GeSe3–CdSe section at 1:1:1 ratio of the initial components, and the Tl2CdGe3Se8 compound forms at the Tl2CdGeSe4–GeSe2 section at the ratio of 1:1:3. This quasi-ternary system contains nine single-phase, seventeen two-phase, and nine three-phase fields. The solid solubility range of CdSe is within 3 mol.% at the Tl4GeSe4–CdSe and Tl2GeSe3–CdSe sections. The existence of the Tl2CdSnSe4 compound was confirmed in the Tl2Se–CdSe–SnSe2 system at 570 K, and the formation of six single-phase, ten two-phase and five three-phase fields was found. The crystal structure of four quaternary compounds, Tl2CdGe3Se8 and three isostructural chalcogenides Tl2CdGeSe4, Tl2CdSiTe4, Tl2HgSiTe4, was determined. Tl2CdGe3Se8 crystallizes in the orthorhombic symmetry, SG P212121, lattice parameters a=0.76023(9), b=1.2071(2), c=1.7474(2) nm. Tl2ВIIDIVX4 crystallizes in the tetragonal structure, SG I-42m. The cell parameters of the compounds are: a=0.80145(9), c=0.67234(9) nm (Tl2CdGeSe4); a=0.8049(6), c=0.68573(8) nm (Tl2CdSnSe4); a=0.84121(6), c=0.70289(9) nm (Tl2CdSiTe4); a=0.83929(4), c=0.70396(5) nm (Tl2HgSiTe4). The dependence of the unit cell volume and the calculated density on the molar mass in eleven previously known and three newly discovered isostructural (SG I-42m) Tl2BIIDIVX4 compounds was considered.
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